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Asymmetric synthesis, stereochemistry, and absolute configuration of 1,2-5-trimethyl-5-(2-cyanoethyl)- and 1,2,5-trimethyl-4-piperidinones

✍ Scribed by G. V. Grishina; E. L. Gaidarova; A. É. Aliev

Publisher
Springer US
Year
1992
Tongue
English
Weight
662 KB
Volume
28
Category
Article
ISSN
0009-3122

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## Abstract The synthesis of specifically labeled 2,5,8‐trimethyl‐3,4‐dihydro‐1(2H)‐naphthalenone‐2‐d and 3,5,8‐trimethyl‐3,4‐dihydro‐1(2H)‐naphthalenone‐2,2‐d~2~ through α‐proton exchange using neat trifluoroacetic acid‐d is described.