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Synthesis and properties of bis-/1,3,5-trimethyl-2,4-dioxohexahydro-1,3,5,-triazinylidene-(6)/

✍ Scribed by A. Pískala


Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
279 KB
Volume
5
Category
Article
ISSN
0040-4039

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✍ Hélio A. Stefani; Adriano S. Vieira; Mônica F.Z.J. Amaral; Leora Cooper 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 761 KB

Herein we report an approach to the formation of 5-alkynyl-1,3-dioxin-4-ones using Suzuki-Miyaura cross-coupling reaction of potassium alkynyltrifluoroborate salts with 2,2,6-trimethyl-5-iodo-1,3dioxin-4-one. The resulting 5-ethynyltrimethylsilyl-1,3-dioxin-4-ones obtained through the Sonogashira re