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Asymmetric synthesis of the (2S,4S,6S)-2,4,6-trimethylnonyl subunit of siphonarienes

✍ Scribed by David D. Diaz; Fernando R. P. Crisóstomo; Víctor S. Martín

Book ID
119922808
Publisher
Laser Pages Publishing Ltd.
Year
2001
Tongue
English
Weight
59 KB
Volume
41
Category
Article
ISSN
0021-2148

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The title compounds were prepared via two efficient routes. The first sequence utilized a diastereospecific triflate alkylation in the key bond forming step while the second method relied on a novel intramolecular Mitsunobu reaction to set the required stereochemistry. Many pharmaceutical agents co