Asymmetric synthesis of syn 1,2-diols via the reaction of aldehydes with chiral .gamma.-(tetrahydropyranyloxy)allylstannanes
โ Scribed by Yamamoto, Yoshinori; Kobayashi, Katsumi; Okano, Hiroshi; Kadota, Isao
- Book ID
- 126819936
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 416 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0022-3263
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Stereoselectivity of aldol reactions between aliphatic aldehydes and Ni(ll)-complex of chiral non-racemic Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone (BPB) in the presence of excess of MeONa, has been studied as a function of time, reaction conditions and nature of an ald
## A stoicbiometric Itmomtofthccbiral~1turntdouttos tlaxssivcly promote the aqmmehic aldol rcactioa of al&hy&s with cd silyl ethers and the rdowitlg asymmettic leductioa in om pot to affcrd syI&l3diols willlbighetity.