## Abstract Methyl 2‐__O__‐benzyl‐6‐deoxy‐3‐__C__‐methyl‐α‐D‐mannopyranoside (2) was synthesized in ten steps by starting from the readily available methyl 2,3‐anhydro‐4,6‐__O__‐benzylidene‐α‐D‐allo‐pyranoside (3). The key step was the stereoselective __cis__‐hydroxylation (cat. osmium(VIII) oxide)
Asymmetric synthesis of methyl 6-deoxy-3-O-methyl-α-l-mannopyranoside from a non-carbohydrate precursor
✍ Scribed by Wenting Du; Yongzhou Hu
- Book ID
- 108080329
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 120 KB
- Volume
- 341
- Category
- Article
- ISSN
- 0008-6215
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