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Asymmetric Synthesis of (−)-Martinellic Acid

✍ Scribed by Davies, Stephen G.; Fletcher, Ai M.; Lee, James A.; Lorkin, Thomas J. A.; Roberts, Paul M.; Thomson, James E.

Book ID: 120199211
Publisher: American Chemical Society
Year: 2013
Tongue: English
Weight: 764 KB
Volume: 15
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol4007508

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📜 SIMILAR VOLUMES

Asymmetric Total Synthesis of Martinelli

Asymmetric Total Synthesis of Martinelline and Martinellic Acid.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Asymmetric total synthesis of martinelli

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The tricyclic triamine core 27 of martinellic acid (2) has been prepared stereospecifically in eight steps from 2-hydroxymethylaniline in 11% overall yield. The key steps are the addition of 2hydroxymethylaniline to vinylcyclopropane 14 to prepare cycloaddition precursor 19 in only two steps and an