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Asymmetric Synthesis of Isothiazoles through Cu Catalysis: Direct Catalytic Asymmetric Conjugate Addition of Allyl Cyanide to α,β-Unsaturated Thioamides

✍ Scribed by Yuka Yanagida; Ryo Yazaki; Dr. Naoya Kumagai; Prof. Dr. Masakatsu Shibasaki

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 541 KB
Volume: 50
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201102467

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## Abstract Key feature of the title conjugate addition reaction is the cooperative activation of both the alkyne and the thioamide by a combined soft Lewis acid—hard Broensted base catalyst system.