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ChemInform Abstract: Cooperative Activation of Alkyne and Thioamide Functionalities; Direct Catalytic Asymmetric Conjugate Addition of Terminal Alkynes to α,β-Unsaturated Thioamides.

✍ Scribed by Ryo Yazaki; Naoya Kumagai; Masakatsu Shibasaki

Publisher
John Wiley and Sons
Year
2011
Weight
80 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Key feature of the title conjugate addition reaction is the cooperative activation of both the alkyne and the thioamide by a combined soft Lewis acid—hard Broensted base catalyst system.

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