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Asymmetric synthesis of cyclohex-2-enols: The examples of seudenol and analogues

✍ Scribed by Ana B. Bueno; M. Carmen Carreño; JoséL. García Ruano; Chafiq Hamdouchi

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
226 KB
Volume
6
Category
Article
ISSN
0957-4166

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Asymmetric Synthesis of (+)-Tanikolide a
Asymmetric Synthesis of (+)-Tanikolide and the β-Methyl-Substituted Analogues of (+)-Tanikolide and (–)-Malyngolide
✍ Robert Doran; Lesley Duggan; Surrendra Singh; Colm D. Duffy; Patrick J. Guiry 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 770 KB

## Abstract The δ‐lactone‐containing natural product (+)‐tanikolide, a brine shrimp toxin and antifungal compound, was synthesized in nine steps with an overall yield of 26.4 % by employing Sharpless asymmetric epoxidation and ZrCl~4~‐catalyzed intramolecular acetalization as the key steps. The nov