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Asymmetric Synthesis of Chiral α-Keto Esters via Grignard Addition to Oxalates.

✍ Scribed by David I. MaGee; Tammy C. Mallais; Marijanna Eic

Publisher
John Wiley and Sons
Year
2004
Weight
111 KB
Volume
35
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric 1,4 Addi
ChemInform Abstract: Asymmetric 1,4 Addition of Grignard Reagents to Chiral α,β-Unsaturated Esters in the Presence of Lewis Acids.
✍ Giuliana Cardillo; Luca Gentilucci; Alessandra Tolomelli; Claudia Tomasini 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Asymmetric 1,4 Addition of Grignard Reagents to Chiral α,β-Unsaturated Esters in the Presence of Lewis Acids. -The reaction proceeds with good yields but variable diastereoselectivities, depending on the organometallic reagent and Lewis acid used. -(CARDILLO, GIULIANA;