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Asymmetric Synthesis of CDP840 by Jacobsen Epoxidation. An Unusual Syn Selective Reduction of an Epoxide

โœ Scribed by Lynch, J. E.; Choi, W.-B.; Churchill, H. R. O.; Volante, R. P.; Reamer, R. A.; Ball, R. G.

Book ID
120631656
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
208 KB
Volume
62
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: Asymmetric Synthesi
ChemInform Abstract: Asymmetric Synthesis of CDP840 by Jacobsen Epoxidation. An Unusual Syn-Selective Reduction of an Epoxide.
โœ J. E. LYNCH; W.-B. CHOI; H. R. O. CHURCHILL; R. P. VOLANTE; R. A. REAMER; R. G. ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 37 KB ๐Ÿ‘ 2 views

Asymmetric Synthesis of CDP840 by Jacobsen Epoxidation. An Unusual Syn-Selective Reduction of an Epoxide. -The catalytic asymmetric synthesis of the PDE (IV) inhibitor, CDP840 (R)-(VI), useful as antiasthmatic agent, is presented. The absolute stereochemistry is controlled by a Jacobsen epoxidation

ChemInform Abstract: An Enantioselective
ChemInform Abstract: An Enantioselective Synthesis of (-)-Allosamidin by Asymmetric Desymmetrization of a Highly Functionalized meso-Epoxide.
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An Enantioselective Synthesis of (-)-Allosamidin by Asymmetric Desymmetrization of a Highly Functionalized meso-Epoxide. -The enantioselective preparation of (XII) represents a formal total synthesis of (-)-allosamidin (XIII). A significant improvement compared to prior approaches affords this inte