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Asymmetric Synthesis of a Chiral Building Block for Cyclopentanoids: A Novel Enantioselective Synthesis of Preclavulone A

โœ Scribed by Zanoni, Giuseppe; Porta, Alessio; Brunoldi, Enrico; Vidari, Giovanni


Book ID
127271691
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
161 KB
Volume
71
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Asymmetric Synthesis of a Chiral Buildin
โœ Giuseppe Zanoni; Alessio Porta; Enrico Brunoldi; Giovanni Vidari ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons โš– 14 KB ๐Ÿ‘ 2 views

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Asymmetric synthesis of (โˆ’)- and (+)-kai
โœ Katsuhiko Tomooka; Toshiyuki Akiyama; Phewluangdee Man; Masaki Suzuki ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

Both enantiomers of kainic acid have been synthesized from enantioenriched planar chiral cyclic amide 2a. The C3 and C4 stereocenters in the pyrrolidine ring were constructed by transannular Cope rearrangement of 2a, and the carboxyl group at the C2 position was introduced through lithiation followe