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Asymmetric synthesis of 1,1,2- and 1,2-substituted dihydronaphthalenes via a chiral naphthyl imine

โœ Scribed by A.I. Meyers; Jack D. Brown; Dominique Laucher

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
192 KB
Volume
28
Category
Article
ISSN
0040-4039

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The synthesis and resolution of 1-(2-methoxy-l-naphthyl)isoquinoline and 1-(2-methylthio-1naphthyl)isoquinoline is reported. These ligands were assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethylmalonate. Enantioselectivity up to