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Asymmetric Syntheses of l,l- and l,d-Di-myo-inositol-1,1′-phosphate and their Behavior as Stabilizers of Enzyme Activity at Extreme Temperatures

✍ Scribed by Christina M. Longo; Yang Wei; Mary F. Roberts; Scott J. Miller

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 665 KB
Volume: 121
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200900480

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✦ Synopsis

Abstract

Hitzeschutz: Die Totalsynthese von l,l‐DIP und l,d‐DIP (siehe Strukturen) beinhaltet als Schlüsselschritt den komplexen Fall einer doppelten asymmetrischen Induktion. Die thermoprotektive Wirkung beider Isomere auf Enzyme wurde untersucht, und beide zeigen biologische Aktivität.magnified image

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