## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Asymmetric syntheses of chiral propane-1,3-diols starting from malonic acid
β Scribed by Ihara, Masataka; Takahashi, Masanobu; Taniguchi, Nobuaki; Yasui, Ken; Fukumoto, Keiichiro; Kametani, Tetsuji
- Book ID
- 121279299
- Publisher
- Royal Society of Chemistry
- Year
- 1989
- Weight
- 982 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1472-7781
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## RI J, 8diketosulfoxides were reduced with DIBAL to CSzrpS, 8-keto j?-hydroxysulfoxides (de>98%) which can be easily transformed into syn or anti chiral L3diols by known procedures. Chit-al 1,3-dials are important building blocks in the synthesis of many natural products. Great efforts have been
nBusP-or cyanide-stabilized RCu.BF3 (R=Me, 4-Me-3-pentenyl) undergo efficient 1,4additions to neopentylether-shielded trans-enoates. Thus chiral B-substituted carboxylic acids e.g. (S)-citronellic acid were obtained in high e.e. (Schemes 2 and 4). Recently greater than 99% enantioselective C-C bond