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Asymmetric sulfur ylide based enantioselective synthesis of D-erythro-sphingosine

✍ Scribed by Morales-Serna, José Antonio; Llaveria, Josep; Díaz, Yolanda; Matheu, M. Isabel; Castillón, Sergio

Book ID
121077566
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
124 KB
Volume
6
Category
Article
ISSN
1477-0520

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In their synthesis of dihydrosphingosine, Rozrsh and Adum [ 131 observed the formation of a I :1 mixture of two isomeric oxazolidinones resulting from an intramolecular transacylation: under our conditions, however, only 9 was obtained. We thank Prof. Dr. W . Roush for a preliminary communication of