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Asymmetric selenomethoxylation of olefins involving a chiral C2 symmetrical electrophilic organoselenium reagent

✍ Scribed by Deziel, Robert; Goulet, Sylvie; Grenier, Louis; Bordeleau, Josee; Bernier, Julie

Book ID
120928208
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
326 KB
Volume
58
Category
Article
ISSN
0022-3263

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Mechanistic aspects of asymmetric cis-di
Mechanistic aspects of asymmetric cis-dihydroxylation of olefins with osmium tetroxide employing a C2-symmetric chiral diamine
✍ Kiyoshi Tomioka; Makoto Nakajima; Yōichi Iitaka; Kenji Koga πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 302 KB

Stereochemical consideration of the eficient enantioselective oxidation of trans-stilbene employing a C2-symmetric chiral diamine (5) strongly indicates an organometallocycle (2) as a possible intermediate in the oxidation of olefns with osmium tetroxide.