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Mechanistic aspects of asymmetric cis-dihydroxylation of olefins with osmium tetroxide employing a C2-symmetric chiral diamine

✍ Scribed by Kiyoshi Tomioka; Makoto Nakajima; Yōichi Iitaka; Kenji Koga

Book ID: 104216414
Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 302 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)80153-7

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✦ Synopsis

Stereochemical consideration of the eficient enantioselective oxidation of trans-stilbene employing a C2-symmetric chiral diamine (5) strongly indicates an organometallocycle (2) as a possible intermediate in the oxidation of olefns with osmium tetroxide.

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