Asymmetric Rhodium-Catalyzed Hydrogenation Meets Gold-Catalyzed Cyclization: Enantioselective Synthesis of 8-Hydroxytetrahydroisoquinolines.
β Scribed by A. Stephen K. Hashmi; Patrick Haufe; Christoph Schmid; Andreas Rivas Nass; Wolfgang Frey
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 48 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
## Abstract The reaction applies a HCOOH/NEt~3~ mixture as a hydrogen source and a chiral Rhβcomplex as a catalyst.
The intention of this short report was to show the advance of theory through a b initio calculations in the field of nitrogen rings. Although the calculated molecular properties can still be extended and refined, already a quite clear picture emerges. Nitrogen rings, and in particular nitrogen cages