The intention of this short report was to show the advance of theory through a b initio calculations in the field of nitrogen rings. Although the calculated molecular properties can still be extended and refined, already a quite clear picture emerges. Nitrogen rings, and in particular nitrogen cages
โฆ LIBER โฆ
Asymmetric Rhodium-Catalyzed Hydrogenation Meets Gold-Catalyzed Cyclization: Enantioselective Synthesis of 8-Hydroxytetrahydroisoquinolines
โ Scribed by A. Stephen K. Hashmi; Patrick Haufe; Christoph Schmid; Andreas Rivas Nass; Wolfgang Frey
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 173 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
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Enantioselective Synthesis of Cyclopentane Derivatives Using Zirconium-Catalyzed Asymmetric Cyclization. -The cyclization of dienes such as (I), (IV), and (VI) in the presence of Bu-MgCl and a chiral Zr-catalyst is studied. Optically active highly substituted cyclopentanes are obtained in good to h