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Asymmetric Reductions. VIII. the Action of the Grignard Reagent from (+)-1-Chloro-2-methylbutane on Cyclohexyl Alkyl Ketones 1

โœ Scribed by Burrows, Elizabeth Parker; Welch, Frank J.; Mosher, Harry S.


Book ID
127074366
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
842 KB
Volume
82
Category
Article
ISSN
0002-7863

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Asymmetric organic reactions, II. Partia
โœ James D. Morrison; Adam Tomash; R.W. Ridgway ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 171 KB

The Grignard reagent from racemic l-chloro-2-phenylbutane has been partially resolved by allowing it to react with less than one equivalent of one of several readily available chiral ketones. Reaction with approximately 0.5 equivalents(2) of (+)-camphor, (-)-fenchone, (-)-menthone or (+)-3-methylcyc