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Asymmetric reduction with chiral NADH model compounds: a dynamic aspect of product stereochemistry

✍ Scribed by Baba, Naomichi; Amano, Masaki; Oda, Junichi; Inouye, Yuzo

Book ID
126162257
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
700 KB
Volume
106
Category
Article
ISSN
0002-7863

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In the reduction of ketones with NADH mimics, (Ss)-l-substituled 3-(p-tolylsulfinyl)-1,4-dihydropyridines 1, the stereospecific transfer of one of the C-4 hydrogens, which is syn to the S-O bond, was experimentally revealed to be involved by employing the 2-methyl derivative 2 and the 4-deuterated d