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Asymmetric Reduction of Ketones by the Acetone Powder of Geotrichum candidum

โœ Scribed by Nakamura, K.; Matsuda, T.

Book ID
115507693
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
193 KB
Volume
63
Category
Article
ISSN
0022-3263

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Asymmetric reductions of (trifluoroacetyl)biphenyl derivatives with bakers' yeast and with Geotrichum candidum acetone powder
โœ Tamotsu Fujisawa; Yoshio Onogawa; Akira Sato; Takeshi Mitsuya; Makoto Shimizu ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 716 KB

The imlmzs' yeast reduction of (trifluore~tyl)biphonyl derivatives produces (R)-trifluoron~thyl biplumylyl carbinols in high cnantiosciectivity, whereas the reduction of the same derivatives with Geotrichum ca~\_'\_d~m acetone powder gives the corresponding (S)-carbinols in excel l ent yields and cn