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Asymmetric Processes Catalyzed by Chiral (Salen)Metal Complexes

✍ Scribed by Larrow, Jay F. ;Jacobsen, Eric N.


Book ID
120968020
Publisher
Springer Berlin Heidelberg
Tongue
English
Weight
666 KB
Category
Article
ISSN
0007-1668

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Alkene aziridination and epoxidation cat
✍ Kenneth J. O'Connor; Shiow-Jyi Wey; Cynthia J. Burrows πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 285 KB

New chiral metal salen complexes substituted in the 3 position with bulky silyl groups (TM!?, TBDMS) have been synthesized. Although some of these complexes catalyzed the epoxidation of unfunctionalized olefins in moderate to high ee's, they catalyzed the aziridination of cis-P-methylstyrene without