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Asymmetric Processes Catalyzed by Chiral (Salen)metal Complexes

✍ Scribed by Jay F. Larrow; Eric N. Jacobsen

Book ID
101973377
Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

πŸ“œ SIMILAR VOLUMES

Alkene aziridination and epoxidation cat
Alkene aziridination and epoxidation catalyzed by chiral metal salen complexes
✍ Kenneth J. O'Connor; Shiow-Jyi Wey; Cynthia J. Burrows πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 285 KB

New chiral metal salen complexes substituted in the 3 position with bulky silyl groups (TM!?, TBDMS) have been synthesized. Although some of these complexes catalyzed the epoxidation of unfunctionalized olefins in moderate to high ee's, they catalyzed the aziridination of cis-P-methylstyrene without