Asymmetric oxidation with furylhydroperoxides
β Scribed by Arrigo Scettri; Francesco Bonadies; Alessandra Lattanzi
- Book ID
- 108036407
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 163 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0957-4166
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π SIMILAR VOLUMES
Furylhydroperoxides can be successfully employed in the enantioselective oxidation of allylic alcohols and sulfides under Sharpless-type conditions. Their kinetic resolution provides a mean both to chiral furylhydroperoxides and furylalcohols. O 1997 Elsevier Science Ltd
A Convenient Approach to Chiral Sulfoxides by Enantioselective Oxidation with a Steroidal Furylhydroperoxide. -Asymmetric oxidation of sulfides as well as kinetic resolution of racemic sulfoxides in the presence of the hydroperoxide shown in the scheme offer efficient routes to chiral sulfoxides. A
AbstractΓEight new bi-o-tolyl bisoxazolines were made and used as ligands in the copper catalyzed asymmetric allylic oxidation reaction. Three benzoyl tert-butyl peresters, p-nitro, o-iodo, and 2,4,6-trichloro were made and used with cyclohexene and cyclopentene with the ligands complexed to copper(