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Asymmetric Nozaki–Hiyama Propargylation of Aldehydes: Enhancement of Enantioselectivity by Cobalt Co-Catalysis

✍ Scribed by Dmitry L. Usanov; Prof. Dr. Hisashi Yamamoto

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
325 KB
Volume
49
Category
Article
ISSN
0044-8249

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## Abstract Dreh‐ und Angelpunkt: Erstmals wurde eine SOMO‐Aktivierung genutzt, um Aldehyde in α‐Stellung zu chlorieren. Diese Umwandlung lässt sich als Teil eines „Linchpin“‐Katalyseprozesses einsetzen, der die enantioselektive Synthese terminaler Epoxide ermöglicht (siehe Schema).magnified image

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