Asymmetric Negishi Reaction for Sterically Hindered Couplings: Synthesis of Chiral Binaphthalenes.
β Scribed by Miroslav Genov; Beatriz Fuentes; Pablo Espinet; Beatriz Pelaz
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 21 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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Asymmetric Synthesis of 2,3-Dihydro-4-pyranones by Reaction of Chiral 3-Alkoxycyclobutanone and Aldehydes. -The cyclobutanone (I) bearing L-ethyl lactate as chiral auxiliary is found to be highly suitable for the preparation of the pyran derivatives with good to excellent e.e. values. -(NEGISHI, S.;