1998 organo-selenium compounds, isocyclic C derivatives organo-selenium compounds, isocyclic C derivatives S 0134 15 -187 Asymmetric Methoxyselenenylation of Alkenes with Chiral Ferrocenylselenium Reagents. -Best results are observed using the ferrocenylselenium compound shown in the scheme. From c
Asymmetric Methoxyselenenylation of Alkenes with Chiral Ferrocenylselenium Reagents
β Scribed by Fukuzawa, Shin-ichi; Takahashi, Kaoru; Kato, Hirohisa; Yamazaki, Hiroshi
- Book ID
- 127029064
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 312 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Very simple, chiral, nonβracemic diselenides were prepared and their corresponding selenium electrophiles were used for the stereoselective functionalization of alkenes. The influence of different alkenes on the outcome of the selenenylation reaction was investigated.
Asymmetric arene-alkene cyclization reactions mediated by a chiral electrophilic organoselenium reagent afforded substituted carbocyclic derivatives with high diastereoselectivities. It was also found that [3-methoxyselenides are good precursors of seleniranium ions when treated with strong acids.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v