𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Asymmetric Methoxyselenenylation of Alkenes with Chiral Ferrocenylselenium Reagents.

✍ Scribed by S. FUKUZAWA; K. TAKAHASHI; H. KATO; H. YAMAZAKI

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
29
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

1998 organo-selenium compounds, isocyclic C derivatives organo-selenium compounds, isocyclic C derivatives S 0134 15 -187 Asymmetric Methoxyselenenylation of Alkenes with Chiral Ferrocenylselenium Reagents.

-Best results are observed using the ferrocenylselenium compound shown in the scheme. From cycloalkenes trans adducts are obtained with good selectivity, while from cis-2-butene the erythro adduct is formed with moderate selectivity. trans-2-Butene gives the threo product with high selectivity (exact configuration is not determined). The reaction with silyl enol ethers yields Ξ±-seleno ketones with moderate to excellent diastereoselectivity. In the presence of the chiral diselenide and (NH 4 ) 2 S 2 O 8 alkenes like (XI) are converted into enols such as (XII) in low optical yields.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Asymmetric Areneβ€”Al
ChemInform Abstract: Asymmetric Areneβ€”Alkene Cyclizations Mediated by a Chiral Organoselenium Reagent.
✍ R. DEZIEL; E. MALENFANT; C. THIBAULT πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

ChemInform Abstract: Asymmetric Synthesi
ChemInform Abstract: Asymmetric Synthesis with Chiral Reagents Derived from Ξ±-Pinene
✍ Vittorio Farina; Gregory P. Roth πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 26 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v