Asymmetric oxidation of olefins to vicin
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Maritherese Tokles; John K. Snyder
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Article
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1986
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Elsevier Science
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French
β 251 KB
High levels of asymmetry can be achieved in the osmium tetroxide cis-hydroxylation of olefins by employing (-)-(R,R)-N,N,N',N'-tetramethylcyclohexane-l,2-traos-diamine as a chiral ligand for the osmium. Osmium tetroxide oxidation of olefins is an excellent method for forming vicinal diols under mil