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Asymmetric induction in the reaction of osmium tetroxide with olefins

✍ Scribed by Hentges, Steven G.; Sharpless, K. Barry


Book ID
115494657
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
401 KB
Volume
102
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Asymmetric oxidation of olefins to vicin
✍ Maritherese Tokles; John K. Snyder πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 251 KB

High levels of asymmetry can be achieved in the osmium tetroxide cis-hydroxylation of olefins by employing (-)-(R,R)-N,N,N',N'-tetramethylcyclohexane-l,2-traos-diamine as a chiral ligand for the osmium. Osmium tetroxide oxidation of olefins is an excellent method for forming vicinal diols under mil