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Asymmetric induction in the diels-alder reactions of α-hydroxyacylnitroso compounds

✍ Scribed by Gordon W. Kirby; Muhammad Nazeer

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
127 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

Transient, chiral u-hydroxyacylnitroso compounds (2), able to form intramolecular hydrogen bonds, react stereoselectively with cyclopentadiene and cyclohexa-1,3-diene; the cycloadduct (6) of the latter diene and the nitroso derivative of (S)-mandelic acid has been converted into the known (-)-oxazine derivative .( 9).

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