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Asymmetric diels - alder reactions with α-chloronitroso compounds - I. Application of α-chloronitroso epiandrosterone in synthesis

✍ Scribed by Mahmud Sabuni; Günter Kresze; Heinz Braun

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
231 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

The Diels -Alder reaction of 1,3-cyclohexadiene (9) with the enanticmerically pure cc-chloronitroso compound 8, synthesized from epiandrosterone-(7a), gives the adduct 10a with l-(R),4-(S) configuration-in 69 % chemical yield andz95 % enazicmeric excess.

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