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Asymmetric hydrosilylation of symmetrical diketones catalyzed by a rhodium complex with trans-chelating chiral diphosphine EtTRAP

✍ Scribed by Ryoichi Kuwano; Masaya Sawamura; Junya Shirai; Masatoshi Takahashi; Yoshihiko Ito


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
204 KB
Volume
36
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Catalytic asymmetric hydrogenation of 1-
✍ Ryoichi Kuwano; Daisuke Karube; Yoshihiko Ito πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 289 KB

A rhodium complex coordinated with a trans-chelating chiral diphosphine (S,S)-(R,R)-PhTRAP was an effective catalyst for asymmetric hydrogenation of N-acyl-1-aza-2-cycloalkene-2-carboxylates, which gave the corresponding protected cyclic or-amino acids with 73-97% ee.