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Asymmetric hydrogenation with the use of chiral carborane amidophosphite derivatives in supercritical carbon dioxide and CH2Cl2

✍ Scribed by S. E. Lyubimov; V. A. Ol’shevskaya; P. V. Petrovskii; E. A. Rastorguev; T. A. Verbitskaya; V. N. Kalinin; V. A. Davankov


Book ID
106521769
Publisher
Springer
Year
2010
Tongue
English
Weight
252 KB
Volume
59
Category
Article
ISSN
1573-9171

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Application of a new amidophosphite liga
✍ Sergey E. Lyubimov; Eugenie A. Rastorguev; Vadim A. Davankov 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 95 KB

## Abstract New chiral amidophosphite ligand was synthesized and tested in the Rh‐catalyzed asymmetric hydrogenation of (__Z__)‐β‐(acylamino)acrylates in protic solvents and supercritical carbon dioxide (scCO~2~) The catalytic performance is affected greatly by the acidity of the solvents. Better e