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Asymmetric Hydrogenation of Olefins with Aprotic Oxygen Functionalities Catalyzed by BINAP-Ru(II) Complexes

✍ Scribed by Ohta, Tetsuo; Miyake, Tsutomu; Seido, Nobuo; Kumobayashi, Hidenori; Takaya, Hidemasa


Book ID
118021470
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
950 KB
Volume
60
Category
Article
ISSN
0022-3263

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Asymmetric hydrogenation of N-tosylimine
✍ AndrΓ©B. Charette; AndrΓ© Giroux πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 French βš– 208 KB

The asymmetric hydrogenation of N-tosylimines was accomplished with a catalytic amount of Ru[(R)-2,2'-bis(diphenylphosphlno)-l,l'-binaphthyl](O2CCH3)2 to afford the corresponding amines in high enantiomeric excesses.