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Asymmetric hydrogenation by an atropisomeric diphosphinite rhodium complex

✍ Scribed by Robert H. Grubbs; Robert A. DeVries


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
121 KB
Volume
18
Category
Article
ISSN
0040-4039

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Investigation into an asymmetric hydroge
✍ Angela Marinetti; SΓ©bastien Jus; Jean-Pierre GenΓͺt πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 249 KB

The bis-phosphetanes 1 and 2 have been used as chiral ligands in the rhodium-catalysed hydrogenations of dehydroamino acid derivatives. An unusual increase of the optical yields at high hydrogen pressures has been noticed. Mechanistic implications are discussed.