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Asymmetric hydroformylation of allylic alcohols catalyzed by Rh(I)-(R,S)-BINAPHOS

✍ Scribed by Kyoko Nozaki; Wen-ge Li; Toshihide Horiuchi; Hidemasa Takaya

Book ID: 104257346
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 208 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00988-x

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✦ Synopsis

Chiral lactones 4a-e were synthesized by the asymmetric hydroformylation of allylic alcohols la-e and 5 catalyzed by a rhodium(1) complex of a chiral phosphine-phosphite, (R,S)-BINAPHOS, followed by the silver(I) oxidation.

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