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Asymmetric Hydroalkynylation of Norbornadienes Promoted by Chiral Iridium Catalysts

✍ Scribed by Prof. Dr. Bao-Min Fan; Qing-jing Yang; Jun Hu; Cai-ling Fan; Si-feng Li; Lu Yu; Dr. Chao Huang; Wing Wai Tsang; Prof. Dr. Fuk Yee Kwong


Book ID
112000361
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
577 KB
Volume
124
Category
Article
ISSN
0044-8249

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Asymmetric allylation of aldehydes with
✍ Antonio Massa; Andrei V. Malkov; Pavel Kočovský; Arrigo Scettri 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 68 KB

Allylation of aldehydes with allyltrichlorosilane in the presence of sulfoxides is reported. The use of excess of (R)-methyl-p-tolylsulfoxide resulted in the formation of the corresponding homoallylic alcohols in good yields and moderate enantiomeric excesses.