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Asymmetric hetero-Diels-Alder reactions. Mechanism of the reaction of alkenyloxazolines with isocyanates

✍ Scribed by Mark C. Elliott; Elbertus Kruiswijk; David J. Willock

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
309 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Diastereomerically pure oxazolo[3,

pyrimidines can be readily prepared by the reaction of alkenyloxazolines with isocyanates. These compounds undergo epimerisation upon prolonged heating. The mechanism of this transformation has been investigated experimentally and computationally.

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