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Asymmetric Epoxidation of α,β-Unsaturated Ketones Catalyzed by Poly(amino Acids)

✍ Scribed by Christelle Lauret; Stanley M. Roberts


Publisher
John Wiley and Sons
Year
2003
Weight
69 KB
Volume
34
Category
Article
ISSN
0931-7597

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Amine-Catalyzed Asymmetric Epoxidation o
✍ Gui-Ling Zhao; Ismail Ibrahem; Henrik Sundén; Armando Córdova 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB

## Abstract The direct organocatalytic enantioselective epoxidation of α,β‐unsaturated aldehydes with different peroxides is presented. Proline, chiral pyrrolidine derivatives, and amino acid‐derived imidazolidinones catalyze the asymmetric epoxidation of α,β‐unsaturated aldehydes. In particular, p