ChemInform Abstract: Asymmetric Epoxidat
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L. H. LI; D. WANG; T. H. CHAN
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Article
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2010
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John Wiley and Sons
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Asymmetric Epoxidation of Nearly Symmetrical cis-Alkenes. Sharpless Epoxidation of (1,2-Dialkyl)vinylsilanols. -Optically active epoxides such as (III) are obtained by asymmetric Sharpless epoxidation of vinylsilanols (II), which are derived by very mild hydrolyzation of the ethers (I). The startin