Enantioselective Synthesis of Deoxymanno
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Marie-CΓ©line Lamas; Max Malacria; Serge Thorimbert
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Article
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2011
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John Wiley and Sons
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English
β 278 KB
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## Abstract An efficient enantioselective synthesis of deoxymannojirimicin is reported. It is based on the unusual Sharpless asymmetric epoxidation of a silylβsubstituted allylic 1,4βamino alcohol coupled with a further highly stereoselective intramolecular aldolization. Both enantiomers of deoxyma