๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The asymmetric epoxidation of tert-butyl substituted allylic alcohols

โœ Scribed by M.J. Schweiter; K.Barry Sharpless

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
205 KB
Volume
26
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

The response of the asymmetric epoxidation reaction to steric bulk in the substrate is tested by use of allylic alcohols with tert-butyl groups at each one of four possible positions.

๐Ÿ“œ SIMILAR VOLUMES

Asymmetric epoxidation of chiral allylic
Asymmetric epoxidation of chiral allylic alcohols
โœ Erwin G.J.C. Warmerdam; Adrianus M.C.H. van den Nieuwendijk; Johannes Brussee; C ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 654 KB

Two series of chiral allylic alcohols, derived from c~,~-unsaturated cyanohydrins, were subjected to asymmetric epoxidation under a variety of conditions. Both achiral (organic peracid, metal-catalyzed peroxide) and chiral (Sharpless titanium-tartrate system) oxidants were applied. Several threo and