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Asymmetric Diels-Alder reactions of (S)-2-(p-tolylsulfinyl)-1,4-naphthoquinones

✍ Scribed by Carreno, M. Carmen; Garcia Ruano, Jose L.; Urbano, Antonio


Book ID
120257971
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
915 KB
Volume
57
Category
Article
ISSN
0022-3263

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Enantioselective Diels-Alder Approach to
✍ M. Carmen Carreño; Antonio Urbano; Claudio Di Vitta 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 166 KB 👁 1 views

Chiral racemic vinylcyclohexenes 2, bearing oxygenated substituents and/or a methyl group at the C-5 position of the cyclohexene ring, were submitted to Diels-Alder reactions with enantiomerically pure (SS)-(2-p-tolylsulfinyl)-1,4-naphthoquinone [(+)-1]. The domino cycloaddition/pyrolytic sulfoxide