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Asymmetric cyclopropanation catalyzed by copper–Schiff’s base complexes

✍ Scribed by Zhengning Li; Zhuo Zheng; Boshun Wan; Huilin Chen


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
95 KB
Volume
165
Category
Article
ISSN
1381-1169

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Asymmetric Cyclopropanation of Styrene C
✍ Zhengning Li; Guosheng Liu; Zhuo Zheng; Huilin Chen 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 121 KB

Asymmetric cyclopropanation of olefins was carried out with chiral copper-Schiff base complexes derived from copper acetate monohydrate, substituted salicylaldehydes and a chiral amino alcohol. Substituents on salicylaldehyde framework demonstrate a significant effect on the steroselectivities. Thos