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✦ LIBER ✦
Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents
✍ Scribed by Alexandre Alexakis; Farida Mhamdi; Franz Lagasse; Pierre Mangeney
- Book ID
- 118606573
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 187 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0957-4166
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Some chiral acetals are cleaved by organoaluminum reagents. The products are formed diastereoselectively, and the removal of the chiral auxiliary affords optically active alcohols. A recent communication by Bartlett, Johnson and Elliott1 on the acetal derived from (-)-(2$4\_R)-2,4-pentanediol has pr
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