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Asymmetric cis-dihydroxylation of olefins by utilizing chiral bispiperazine

✍ Scribed by Kaoru Fuji; Kiyoshi Tanaka; Hisashi Miyamoto

Book ID
103403892
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
258 KB
Volume
33
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Mechanistic aspects of asymmetric cis-di
Mechanistic aspects of asymmetric cis-dihydroxylation of olefins with osmium tetroxide employing a C2-symmetric chiral diamine
✍ Kiyoshi Tomioka; Makoto Nakajima; Yōichi Iitaka; Kenji Koga πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 302 KB

Stereochemical consideration of the eficient enantioselective oxidation of trans-stilbene employing a C2-symmetric chiral diamine (5) strongly indicates an organometallocycle (2) as a possible intermediate in the oxidation of olefns with osmium tetroxide.