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Asymmetric amination of butadiene by secondary amines, catalyzed-by low-valence nickel chiral complexes

โœ Scribed by U. M. Dzhemilev; R. N. Fakhretdinov; A. G. Telin; G. A. Tolstikov; A. A. Panasenko; E. V. Vasil'eva

Book ID
112443023
Publisher
Springer
Year
1980
Tongue
English
Weight
418 KB
Volume
29
Category
Article
ISSN
1573-9171

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Asymmetric allylic amination catalyzed b
Asymmetric allylic amination catalyzed by chiral ferrocenylphosphine-palladium complexes
โœ Tamio Hayashi; Kohei Kishi; Akihiro Yamamoto; Yoshihiko Ito ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 298 KB

A palladium complex bearing chiml (hydroxyalkyl)ferrocenylphosphine ligand was found to be a highly regio-and stereoselective catalyst for the asymmetric allylic amination of 2butenyl acetates with benzylamine, the nucleophilic attack of the amine taking place selectively on the more substituted end