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Asymmetric Allyltributylstannane Addition to Ketones Catalyzed by Chiral PYBOX—In(III) Complex Immobilized in Ionic Liquid.

✍ Scribed by Jun Lu; Shun-Jun Ji; Yong-Chua Teo; Teck-Peng Loh

Publisher
John Wiley and Sons
Year
2006
Weight
25 KB
Volume
37
Category
Article
ISSN
0931-7597

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Asymmetric Allyltributylstannane Additio
Asymmetric Allyltributylstannane Addition to Ketones Catalyzed by Chiral Indium(III)-PYBOX Complex
✍ Jun Lu; Shun-Jun Ji 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 51 KB

## Abstract An indium complex of chiral pyridine bis(oxazoline) (PYBOX) has been applied to the catalytic asymmetric allylation of ketones. It has been found that this chiral indium complex is strong enough to promote the reaction of ketones with allyltributylstannane smoothly. The products were ob